You repot most tropicals when they are dormant. Although thye do not have a period that they drop their leaves (Although they could if they are not from rainforest environment; Then typically lack of water causes leaf drop). In any case, most tropical trees also have a period during which the are not extending branches.
Baobabs is a dificult one; Being a succulent, I would think you would have to let them dry out till leaf drop. Repot, and keep dry only misting. But absolutely no reason to think this, besides it being a succulent from very in many cases very seasonal ranges