There seems to be a little confusion between acid and basic/alkaline here. Concrete is basic due to alkaline compounds in the cementing material. Alkaline materials dissolved in water result in a high pH measurement. Acid is low on the pH scale and it can dissolve the bonds in concrete. So, basically (pun intended) acid loving plants should not be planted in concrete because the leachate (Salts/lime) from the concrete can raise the pH of the soil to a point that they may not thrive. The high pH messes with the roots of the acid loving plants to the point that they don't successfully take in water and nutrients. Elms and Katsura, among others, prefer a pH above 7 (7 being the neutral point). They are good candidates for using an unprotected concrete pot. Acid < 7 < Basic.
Repeatedly soaking, drying, and rinsing can remove some of the excess lime. Sealing the pot with concrete a sealant should greatly reduce the pH changes.
I don't know if the Sealants have adverse effects on plants.